  |
Conductivities of alkyl trimethyl ammonium bromides (alkyl = hexyl-, octyl-, decyl-, dodecyl-, tetradecyl-, hexadecyl-, and octadecyl-) in aqueous solutions were measured as a function of molarity of surfactants, length of chain and temperature. Critical micelle concentrations (CMC) were estimated from the dependence of the specific conductivity on molarity of the surfactants. It was determined that the temperature dependence of CMC is U-shaped with a minimum shifting toward higher temperatures with decreasing chain length of the alkyl group. Quantities characterizing behaviors of surfactants below and above CMC were calculated and compared from conductivity measurements. Measured and calculated values of studied compounds were also compared with results of many other authors. The paper has the form of a minireview. It is a comparison of the presented experimental data of alkyltrimethylammonium bromides (C6– C18) with earlier works reported.
From Jarmila Oremusová
(Received 16.10.2011; revised 10.12.2011)
Appeared in Tenside Surfactants Detergents 2012/03, Page 231-240
Direct link: http://www.tsd-journal.com/TS110187
Pay content
Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions – Part 1: Critical Micelle Concentration (CMC) and Ionization Degree [426 KB]
Free access for subscribers.
References
1 Rosen, M. J.: Characteristic Features of Surfactants, in: Surfactant and Interfacial Phenomena, A Wiley-Interscience Publication, 2ndEdition, Wiley (1989), 1–32.
2 McBain, J. W.: Trans. Faraday Soc. 9 (1913) 99–101.
3 Tanford, C.: The Hydrophobic Effect: Formation of Micelles and Biological Membranes, 2ndrevised edition, John Wiley & Sons, New York (1980).
4 Mukerjee, P.: Adv. Colloid Interface Sci. 1 (1967) 241–245.
5 Esposito, C., Colicchio, P., Facchiano, A. and Ragone, R.: J. Colloid Interface Sci. 200 (1998) 310–312.
6 Abe, M., Kato, K. and Ogino, K.: J. Colloid Interface Sci. 127 (1989) 328–335.
7 Kato, T., Iwai, M. and Seimiya, T.: J. Colloid Interface Sci. 130 (1989) 439–447.
8 Asakawa, T., Johten, K., Miyagishi, M. and Nishida, M.: Langmuir 4 (1988) 136–140.
9 Huibers, P. D. T., Lobanov, V. S., Katritzky, A. R., Shah, D. O. and Karelson, M.: Langmuir 187 (1997) 113–120.
10 Corti, M. and Degiorgio, V.: Physics of Amphiphiles: Micelles, Vesicles and Microemulsions, Elsevier Science Ltd, North-Holland (1985).
11 Lindman, B. and Wennerstrom, H.: Topics in Current Chemistry 87, Springer Berlín (1979).
12 Hassan, S., Rowe, W. and Tiddy, G. J. T.: Handbook of Applied Surface and Colloid Chemistry Ed. Krister Holmberg John Wiley & Sons, New York (2001) Chapter 21/3.
13 Moroi, Y.: Micelles–Theoretical and Applied Aspects Plenum Press New York (1992) Chapter 4.
14 Kallay, N., Tomašic, V., Žalac, S. and Chittofrati, A.: Colloid Polymer Sci. 272 (1994) 1576–1581.
15 Pérez-Rodriguez, M., Prieto, G., Rega, C., Varela, L. M., Sarmiento, F. and Mosquera, V.: Langmuir 14 (1998) 4422–4426.
16 Shah, S. S., Saeed, A. and Sharif, Q. M.: Colloids Surf. A Phys. Chem. Eng. Aspects 155 (1999) 405–412.
17 Caboi, F., Chittofrati, A., Lazzari, P. and, Monduzzi, M.: Colloid Surf. A Phys. Chem. Eng. Aspects 160 (1999) 47–56.
18 Wurtz, J., Meyer, J. and Hoffmann, H.: Phys. Chem. 3 (2001) 3132– 3139.
19 Mosquera, V., del Rio, J. M., Attwood, D., Garcia, M., Jones, M. N., Prieto, G., Suarez, M. J. and Sarmiento, F.: J. Colloid Interface Sci. 206 (1998) 66–76.
20 Scott, A. B. and Tartar, H. V.: J. Am. Chem. Soc. 65 (1943) 692–698.
21 Zielinski, R.: J. Colloid Interface Sci. 235 (2001) 201–209.
22 Zielinski, R., Ikeda, S., Nomura, H. and Kato, S. J.: J. Colloid Interface Sci. 129 (1989) 175–184.
23 De Lisi, R., Ostiguy, D., Perron, G. and Desnoyers J. E.: J. Colloid Interface Sci. 71 (1979)147–166.
24 Woolley, E. M. and Burchfield, T. E.: J. Phys. Chem. 88 (1984) 2149–2163.
25 Adderson, J. E., Taylor, H.: J. Pharm. Pharmacol. 23 (1971) 311 – 312.
26 Evans, D. F., Allen. M., Ninham, B. W. and Fouda, A.: J. Solution. Chem. 13 (1984) 87 –101.
27 Archer, D. G.: J. Solution. Chem. 15 (1986) 581–596.
28 Bashford, M. T. and Woolley, E. M.: J. Phys. Chem. 89 (1985) 3173–3179.
29 Shick, M. J.: J. Phys. Chem. 67 (1963) 1796–1800.
30 Emerson, M. F. and Holtzer, A.: J. Phys. Chem. 71 (1967) 1898–1907.
31 Jones, M. N. and Piercy, J.: J. Chem. Soc. Faraday Trans.1 Phys. Chem. Condensed Phase. 68 (1972) 1839–1848.
32 Zana, R.: J. Colloid Interface Sci. 78 (1980) 330–337.
33 Evans, D. F. and Wightman, P. J.: J. Colloid Interface Sci. 86 (1982) 515–524.
34 Archer, D. G.: J. Solution Chem. 16 (1987) 347–365.
35 Kallay, N., Tomišic, V., Hrust, V., Pieri, R. and Chittofrati, A.: Colloid Surf. A Phys. Chem. Eng. Aspects 222 (2003) 95–101.
36 Chauhan, M. S., Kumar, G., Kumar, A., Sharma, K. and Chauhan, S.: Colloid Surf. A Phys. Chem. Eng. Aspects 180 (2001) 111–119.
37 Chauhan, M. S., Sharma, K., Kumar, G. and Chauhan, S.: Colloid Surf. A Phys. Chem. Eng. Aspects 221 (2003) 135–140.
38 Kang, K.-H., Kim, H.-U. and Lim, K.-H.: Colloid Surf. A Phys. Chem. Eng. Aspects 189 (2001) 113–121.
39 Mehta, S. K., Bhasin, K. K., Chauhan, R. and Dham, S.: Colloid Surf. A Phys. Chem. Eng. Aspects 255 (2005) 153–157.
40 Fujiwara, M., Okano, T., Nakashima, T. H., Nakamura, A. A. and, Sugihara, G.: Colloid Polym. Sci. 275 (1997) 474–481.
41 Gonzales-Perez, A., Czapkiewicz, J., Del Castillo, J. L. and Rodriguez, J. R.: Colloids Surf. 232 (2004) 183–189.
42 Moulik, S. P., Haque, Md. E., Jana, P. K. and, Das, A. R.: J. Phys. Chem. 100 (1996) 701–708.
43 Robinson. R. A. and Stokes, R. H.: Electrolyte Solutions, Butterworths, London (1959) p. 537.
44 Matta, J., Varade, D. and Bahadur, P.: Thermochimica acta 428 (2005) 147– 155.
45 Becher, P., in Shick, M. J. (Ed), Nonionic Surfactants, Marcel Dekker, New York (1967) Chapter 15.
46 Kim, H.-U. and, Lim, K.-H.: Colloid Surf. A Phys. Chem. Eng. Aspects 235 (2005) 121–128.
47 Corrin, M. L. and, Harkins, W. D.: J. Am. Chem. Soc. 64 (1947) 683–688.
48 Asakawa, T., Kitano, H., Ohta, A. and Miyagishi S.: J. Colloid Interface Sci. 242 (2001) 284–287.
49 Bakshi, M. S.: J. Colloid Interface Sci. 227 (2000) 78–83.
50 La Mesa, C.: Colloid Polym. Sci. 268 (1990) 959–964.
51 Stauff, J.: Kolloid Zeitschrift and Zeitschrift für Polymere. 227 (1968) 55–65.
52 Klevens, H. B.: J. Am. Chem. Soc. 30 (1953) 74–80.
53 Texter, J.: Encyclopedie of Chemical Physics and Physical Chemistry Ed. Moore, J. H., Spencer N. D. New York (2001) Chapter C 2.3.
54 Lindman, B.: Handbook of Applied Surface and Colloid Chemistry Ed. Krister Kolmberg, John Wiley & Sons New York (2001) Chapter 19.
55 Ruso, J. M., Attwood, D., Taboada, P. and Mosquera V.: Colloid Polym. Sci. 280 (2002) 336–341.
56 Ruso. J. M. and, Sarmiento, F.: Colloid Polym. Sci. 278 (2000) 800–804.
57 Haydon D. A., Taylor, F. H. and, Kato, S.: Trans. Faraday Soc. 58 (1962) 1233.
58 Zana, R., Yiv, S., Strazielle, C. and Lianos, P.: J. Colloid Interface Sci. 80 (1981) 208.
59 Graber, E., Land, J. and Zana, R.: Kolloid Z. Z. Polym. 238 (1970) 470.
60 Patist, A.: Handbook of Applied Surface and Colloid Chemistry Ed. Krister Kolmberg, John Wiley & Sons New York (2001) Chapter 13.
61 Winnik, F. M. and Regismond, T. A.: Colloid Surf. A Phys. Chem. Eng. Aspects 118 (1996) 121.
62 Hirata, H., Yagi, Y. and Imura, N.: J. Colloid Interface Sci. 173 (1995) 151.
63 Gamboa, C. and, Olea, A. F.: Colloid Surf. A Phys. Chem. Eng. Aspects 278 (2006) 241–245.
64 Basu Ray, G., Chakraborty, I., Ghosh, S., Moulik, S. P. and Palepu, R.: Langmuir 21 (2005) 10958–10967.
65 Ribeiro, A. C. F., Lobo, V.M.M., Valente, A. J.M., Azevedo, E. P. G., Miguel, M. da G. and Burrows, H. D.: Colloid Polym. Sci. 283 (2004) 277.
66 Bakshi, M. S.: Colloid Polym. Sci. 278 (2000) 524.
67 Everaars, M. D., Marcelis, A. T. M., Kuypers, A. J., Laverdure, E., Koronova, J., Koudys, A. and Sudholter, J. R.: Langmuir 11 (1995) 3705.
68 Causi, S., De Lisi, R., Milioto, S. and Tirone, N.: J. Phys. Chem. 95 (1991) 5664.
69 Mc Grath, K. M.: Langmuir 11 (1995) 1835.
70 Markina, Z. N., Panicheval, L. P. and Zadymova, N. N.: Colloid J. 58 (1996) 744.
71 Rozycka-Rozsak, B., Zylka, R. and Sarapuk, J.: Z. Naturforsch. 55 (2000) 413.
72 Mc Lachlan, A. A. and Marangoni, D. G.: J. Colloid Interface Sci. 295 (2006) 243–248.
73 Jalšenjak, N. and Težak, D.: Chem. Eur. J. 10 (2004) 5000–5007.
74 Chakraborty, T., Goesh, S. and Moulik, S. P.: J. Phys. Chem. B 109 (2005) 14 813.
75 Asakawa, T., Kitano, H., Ohta, A. and Mizagishi, S.: J. Colloid Interface Sci. 242 (2001) 284–287.
76 Bakshi, M. S.: J. Colloid Interface Sci. 227 (2000) 78–83.
77 Gharibi, H., Razavizadeh, B. M. and Hashemianzaheh, M.: Colloid Surf. A Phys. Chem. Eng. Aspects 174 (2000) 375–386.
78 Lee, Y. S. and Woo, K. W.: J. Colloid Interface Sci. 169 (1995) 34–38.
79 Carnero Ruiz, C., Diaz-Lopez, L. and Aguiar, J.: J. Colloid Interface Sci. 305 (2007) 293–300.
80 Durand-Vidal, S., Jardat, M., Dahirel, V., Bernard, O., Perrigaud, K. and Turq, P.: J. Phys. Chem. B 110 (2006)15542–15547.
81 Changi, R., de Ménorval, L.-C., Charnay, C., Derrien, G. and Zajac, J.: J. Colloid Interface Sci. 326 (2008) 227–234.
82 Jiang, N., Wang, Y., Wang, J., Yan, H. and Thomas, R.-K.: J. Colloid Interface Sci. 286 (2005) 755–760.
83 Feitosa, E., Brazolin, M. R. S., Naal, R. M. Z. G., Freire de Morais Del Lama, M. P., Loh, W. and Vasilescu, M.: J. Colloid Interface Sci. 299 (2006) 83–839.
84 Para, G., Jarek, E. and Warszynski, P.: Advances in Colloid and Interface Science 122 (2006) 39–55.
85 Modaressi, A., Sifaoui, H., Grzesiak, B., Solimando, R., Domanska, U. and Rogalski, M: Colloid Surf. A Phys. Chem. Eng. Aspects 296 (2007) 104–108.
86 Lee, D. J.: Colloid Polym. Sci. 273 (1995) 539.
87 Greksáková, O. and Oremusová, J.: Tenside Surfactants Deteregents 39 (2002) 40.
88 Ali, A. and Nain, A. K.: J. Surf. Sci. Technol. 13 (1997) 1.
89 Tanford, C.: J. Phys. Chem. 78 (1974) 2649.
90 Shah, S. S., Jamroz, N. U. and Sharif, Q. M.: Colloid Surf. A: Phys. Chem Eng Aspects 178 (2001) 199–206.
91 Korössyová, Z. and Zathurecký, L.: Pharmazie 26 (1971) 682–685.
92 Korössyová, Z., Mandák, M. and Zathurecký, L.: Acta Fac. Pharm. Univ. Comenianae 23 (1973) 91–118.
|
| © 2013 by Carl Hanser Verlag |
Navigation
- Current issue
- Volumes
- Search
- Top 20 Downloads
Subscriber Support
abo-service@hanser.de
For authors:
Information on article submission
- Volumes
- Search
- Top 20 Downloads
Subscriber Support
abo-service@hanser.de
For authors:
Information on article submission
Document number